Windows 10: Two people, one PC, how to isolate programs

Okay so me and my wife are using the same PC and we both stream on twitch. We both like using the same program for streaming. The main problem with streaming programs is if you make changes it impacts every other profile. This gets compounded further as when you make changes on the PC itself sometimes it’ll carry over those changes to every other person on the system which can break setups. IE: changing defaults for microphones/sound outputs, input pass through, etc.We are about to upgrade to a new PC and go to windows 11 pro and finally have separate user accounts. Is there any possible way t

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Why did the startup window get cleared?

I didn't missed any step, the list was gone and gone , even after using lot of programs the programs were not listed in that list.

 

Sound Isolating Earphones

Sound Isolating earphones preferred as I already have a good pair of cans, but open to all suggestions.

 

Clear "Pin suggested" list in People Bar

Does anybody know how to clear the "Pin suggested" list on the "People bar"?

Contacts are added to the "Pin suggested" list once you've pinned and unpinned them. But there seems to be no obvious way to remove them from that list.

After playing around with this feature and pinning and unpinning many dummy contacts, it's rather annoying to see them in the "Pin suggested" list when you click on the "My People" icon in the taskbar.